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Michler's ketone
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Michler's ketone : ウィキペディア英語版
Michler's ketone

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Michler’s ketone is an organic compound with the formula of ()2CO. This electron-rich derivative of benzophenone is an intermediate in the production of dyes and pigments, for example Methyl violet. It is also used as a photosensitizer. It is named after the German chemist Wilhelm Michler.
==Synthesis==
The ketone is prepared today as it was originally by Michler using the Friedel-Crafts acylation of dimethylaniline (C6H5NMe2) using phosgene (COCl2) or equivalent reagents such as triphosgene (Me = methyl):
:COCl2 + 2 C6H5NMe2 → (Me2NC6H4)2CO + 2 HCl
The related tetraethyl compound (Et2NC6H4)2CO, also a precursor to dyes, is prepared similarly.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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